2 / 2022-06-02 08:53:28
Chemical fuel driven transient polymeric micelles nanoreactors toward reversible trapping and reaction acceleration
polymeric micelle, dissipative self-assemble, transient nanoreactor
摘要待审
XianhuaLang / University of Electronic Science and Technology of China
ZhaoHui / a. Institute of Fundamental and Frontier Sciences (IFFS), University of Electronic Science and Technology of China (UESTC)
In most synthetic nanoreactor systems, catalyzed products cannot diffuse out of the nanoreactor in time leading to lower catalytic efficiency than expected. To address the diffusion problem, transient polymer micelles nanoreactors system were achieved by using 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) as the fuel and activated esters as energy dissipating units, demonstrating the pathway dependent catalytic properties for the transient micelles: the product inhibition was observed or could be efficiently eliminated depending on re-loading EDC in the metastable stage or after the full dissipation for transient micelles.
重要日期
  • 会议日期

    07月01日

    2022

    07月03日

    2022

  • 06月24日 2022

    初稿截稿日期

  • 07月01日 2022

    注册截止日期

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